A sample keeps a definite volume but takes the shape of whatever container holds it. Which state of matter best describes the sample?
05/14 Intermolecular Forces and Phases of Matter Online Quiz Questions
Use this free practice quiz with 20 questions to review 05/14 Intermolecular Forces and Phases of Matter, test your knowledge, and prepare for your next test or exam.
True or false: During an ordinary phase change, the covalent bonds within each molecule are generally broken.
- A
True
- B
False
At the same temperature, a liquid with stronger intermolecular attractions generally has vapor pressure.
What phenomenon causes water to rise in a narrow, clean glass tube when adhesion to the glass helps draw the liquid upward?
Two isomers have the same molecular formula and similar polarity. Which isomer will generally have stronger London dispersion attractions and a higher boiling point?
- A
The more-branched isomer, because branching always increases contact area
- B
The less-branched isomer, because it usually has a larger contact area
- C
Both must have identical boiling points because their formulas are the same
- D
The more-branched isomer, because compact molecules always have more electrons
Select all of the phase changes that are endothermic.
- A
Melting
- B
Vaporization
- C
Sublimation
- D
Freezing
- E
Condensation
- F
Deposition
True or false: On a heating-curve plateau, added heat primarily increases intermolecular potential energy while the average kinetic energy remains constant.
- A
True
- B
False
How much heat is absorbed when 3.00 mol of ice melts at its melting point? Use (ΔHfus=6.01 kJ mol−1) and report the value in kJ.
Which condition defines the boiling point of a liquid at a particular external pressure?
- A
When the liquid has no intermolecular attractions remaining
- B
When the liquid reaches exactly 100 °C under every condition
- C
When the liquid's vapor pressure equals the external pressure
- D
When all molecules in the liquid have the same kinetic energy
Select all properties that are characteristic of ionic solids.
- A
They typically have high melting points.
- B
They are generally brittle.
- C
They conduct electricity when molten or dissolved.
- D
They are typically malleable and ductile as solids.
- E
They are usually good electrical conductors as solid crystals.
Hydrogen bonding can occur when hydrogen is covalently bonded to .
Explain why water's solid–liquid boundary slopes slightly to the left on a phase diagram. Relate the unusual slope to the densities of ice and liquid water and to the effect of increasing pressure.
True or false: Because ice is less dense than liquid water, increasing pressure can favor melting under appropriate conditions.
- A
True
- B
False
On a phase diagram, what point marks the end of the liquid–gas boundary, beyond which no amount of pressure can produce an ordinary liquid above the critical temperature?
- A
The triple point
- B
The critical point
- C
The normal boiling point
- D
The melting point
A sample has a definite volume, takes the shape of its container, and consists of particles that remain close together while moving past one another. Which state of matter best describes the sample?
- A
The particles are widely separated and the substance has neither a definite shape nor a definite volume.
- B
The particles remain close together but can move past one another, so the substance has a definite volume but no definite shape.
- C
The particles vibrate about fixed positions, so the substance has a definite shape and volume.
- D
The particles are completely stationary and occupy no volume.
Which intermolecular force must be present between two nonpolar molecules?
- A
Only hydrogen bonding
- B
Only dipole–dipole attraction
- C
London dispersion forces
- D
Ion–dipole attraction
Why do small droplets of a liquid tend to be approximately spherical?
- A
Surface molecules experience a net inward attraction that favors a smaller surface area.
- B
Surface molecules have no intermolecular attractions and therefore spread indefinitely.
- C
Surface molecules are held in place by covalent bonds to the air.
- D
Surface molecules move faster than all molecules inside the liquid.
A solid is brittle, has a high melting point, and conducts electricity when molten but not as a solid. Which type of solid is it most likely to be?
- A
Molecular solid
- B
Metallic solid
- C
Network covalent solid
- D
Ionic solid
How much energy is required to vaporize 2.00 mol of water at its boiling point if ΔH_vap = 40.7 kJ/mol? Enter the value in kJ. Use zero absolute tolerance.
A 250.0 g sample of water is warmed from 20.0 °C to 35.0 °C. What amount of heat is absorbed? Use c=4.18 J g−1 ∘C−1. Enter your answer in kJ. Answers within 0.1 kJ of the reference value are accepted.